Regio- and Stereoselective Oxysulfonylation of Allenes.
نویسندگان
چکیده
A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical process.
منابع مشابه
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عنوان ژورنال:
- Organic letters
دوره 18 16 شماره
صفحات -
تاریخ انتشار 2016